Determination of the selenium (VI)/(IV) standard redox potential by cyclic voltammetry

Determination of selenium by catalytic cathodic stripping voltammetry

A procedure is described for the determination of selenium in natural waters using cathodic stripping voltammetry in the presence of rhodium. Advantage is taken from a catalytic effect on the electrochemical reduction of protons in the presence of a mixed complex of selenide with rhodium and chloride, containing Cl–Rh–SeH species. The catalysis causes a very large peak-current at a negative pea...

Determination of the absolute redox potential of methyldopa: experimental and simulation methodes

The conditional formal potential, E°′of Methyldopa has been studied by cyclic voltammetry at the surface of activated glassy carbon electrode (AGCE) as the working electrode in different pH phosphate buffered solutions. The experimental Standard redox potential, E°′, of Methyldopa is obtained to be 0.72 mV versus SHE (Standard Hydrogen Electrode). E°′ values have also been calculated with the a...

Cyclic Voltammetry

Collectorless flotation of Chalcocite by controlling redox potential

Using microflotation method, this study explored the collectorless flotation of Chalcocite and its dependence on the redox potential of pulp . Electrochemical studies were performed by cyclic voltammetry  in specific potential ranges and at different pH values. The results show that significant floatability of Chalcocite occurs in the specific reducing conditions. By increasing potentials, on t...

Cyclic Voltammetry of Auranofin

The oxidative behavior of Auranofin, 2,3,4,6-tetra-O-acetyl-1-thio-beta-D-glucopyranosato- S(triethylphosphine)gold(I), was investigated by using cyclic voltammetry (CV) in 0.1 M Bu(4)NPF(6)/CH(2)Cl(2) and 0.1 M Bu(4)NPF(4)/CH(2)Cl(2) solutions using Pt working and auxiliary electrodes and a Ag/AgCI reference. CV studies at scan rates from 50-2,000 mV/s and Auranofin concentrations between 1 an...